Volume 156
Main Index

Issue 1, Pages 1-278 (15 August 1978)

Preface Page ix Colin Eaborn, Ernst Otto Fischer, Jean F. Normant, Oleg A. Reutov, Dietmar Seyferth

Scientific Contributions of Professor Herbert C. Brown Pages ix-xv Ei-Ichi Negishi

Symmetrical exchange of potassium trialkylborohydrides with trialkylboranes, direct observation of steric effects by 11B NMR spectroscopy Pages C17-C19 Charles A. Brown

Direct alkylation of allylic alcohols with allylic rearrangement using a new alkylating reagent, RCu: BF3 Pages C9-C11 Yoshinori Yamamoto, Kazuhiro Maruyama

Stereochemistry of the allene in the conversion of ethynylalkanol acetates into allenes via organoboranes Pages C5-C8 M. Mark Midland, Deborah C. McDowell

Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes Pages C20-C24 David E. Van Horn, Louis F. Valente, Michael J. Idacavage, Ei-Ichi Negishi

Vinylmetalloids : II. The high regioselectivity of dialkylboranes in the hydroboration of vinyltrimethylsilane Pages C12-C16 John A. Soderquist, Alfred Hassner

Molecular addition compounds of N,N,N′,N′-tetramethylethylenediamine with boron trifluoride and monoalkylboranes Pages C1-C4 B. Singaram, John R. Schwier

An electrostatic model of methyllithium tetramer, a non-nonclassical system Pages 1-3 Andrew StreitwieserJr.

Steric effects in the metalations of 1,1-di-p-tolylethane. Kinetic vs. equilibrium control Pages 5-16 Shelton Bank, John S. Sturges

Formation of free radicals in the reaction of alkyllithiums with titanium tetrachloride Pages 17-23 Glen A. Russell, Davis W. Lamson

Reactions in solutions under pressure : L. Volume change during the solvent separation of the sodium naphthalenide tight ion pair in tetrahydrofuran Pages 25-31 W. J. Le Noble, P. Staub

A theoretical study of cyclooctatetraeneberyllium Pages 33-36 Andrew StreitwieserJr., James E. WilliamsJr.

Markovnikov hydration of vinylcyclopropanes by oxymercuration-demercuration. Pages 37-44 Shinya Nishida, Takashi Fujioka, Nobujiro Shimizu

Mercury in organic chemistry : XVI. Synthesis of 1,4-dienes via allylation of vinylmercurials Pages 45-54 R. C. Larock, J. C. Bernhardt, R. J. Driggs

Organoaluminum chemistry and its application to the initiation of carbenium ion polymerization Pages 55-64 S. Sivaram

A new oxidation procedure for organoaluminum compounds [1] Pages 65-69 George W. Kabalka, Ray J. NewtonJr.

An improved synthesis of cis-alkenylboranes Pages 71-79 James B. CampbellJr., Gary A. Molander

11B NMR studies : I. Reactions of dialkylboranes with organolithium reagents Pages 81-94 John L. Hubbard, Gary W. Kramer

New reactions and reagents. : VIII. A novel general synthesis of dialkylboranes and their derivatives via the transformations of dialkyl(diethylamino)boranes Pages 95-99 Shyam K. Gupta

Diphenylborane. A new hydroborating agent. Synthesis of alkyldiphenylboranes and their application to the conjugate addition reaction of organoboranes Pages 101-110 Peyton JacobIII

Facile reaction of potassium hydride with trialkylboranes, a convenient general synthesis of simple and hindered potassium trialkylborohydrides under exceptionally mild conditions Pages 111-121 Charles A. Brown, S. Krishnamurthy

The reaction of α-methoxyvinyllithium with trialkylboranes Pages 123-132 Alan B. Levy, Steven J. Schwartz, Nancy Wilson, Bradley Christie

Organoboranes in organic synthesis : IX. Carbonylation products of organoboranes derived from myrcene Pages 133-147 Roger Murphy, Rolf H. Prager

Cleavage of α-(phenylthio)alkylboranes with N-chlorosuccinimide. A convenient route to monothioacetals and acetals Pages 149-157 Abel Mendoza, Donald S. Matteson

Synthesis of 1,4-disubstituted (E,Z)-1,3-dienes from lithium dicyclohexyl(trans-1-alkenyl)(1-alkynyl)borates Pages 159-170 George Zweifel, Stephen J. Backlund

Rapid reduction of alkyl tosylates with lithium triethylborohydride. A convenient and advantageous procedure for the deoxygenation of simple and hindered alcohols. Comparison of various hydride reagents Pages 171-181 S. Krishnamurthy

Anomalies in the asymmetric hydroboration of olefins with the adduct of (+)-α-pinene and BH3 · THF Pages 183-190 Arun K. Mandal, Nung Min Yoon

Hydroboration; An ab initio study of the reaction of BH3 with ethylene Pages 191-202 Timothy Clark, Paul v. R. Schleyer

The reaction of B-alkyl-9-borabicyclo[3.3.1]nonanes with aldehydes and ketones. A facile elimination of the alkyl group by aldehydes Pages 203-211 M. Mark Midland, Alfonso Tramontano, Stephen A. Zderic

The hydroboration of 3-butenyl derivatives with 9-borabicyclo[3.3.1]nonane Pages 213-219 Jackson Chi-San Chen

B-bromo-9-borabicyclo[3.3.1]nonane. A convenient and selective reagent for ether cleavage Pages 221-226 M. Vivekananda Bhatt

Vinylmetalloids : I. Coupling reactions of group IV metalloidal halides with magnesium in tetrahydrofuran Pages 227-233 John A. Soderquist, Alfred Hassner

Chloroplatinic acid catalyzed additions of silanes to isoprene Pages 235-244 Robert A. Benkeser, Frederick M. MerrittII, Robert T. Roche

Rotation and inversion barriers in 2-lithio-2-phenyl-1,3-dithianes Pages 245-252 Lee F. Kuyper, Ernest L. Eliel

Synthesis of novel sulfur containing spirocyclic phosphoranes Pages 253-258 Arjun C. Sau, Robert R. Holmes

13C NMR spectra of η3 -allylmanganesetetracarbonyl compounds; structural implications Pages 259-264 Adriaan Oudeman, Ted S. Sorensen

Reactions of AlCl3 and AlBr3 σ-complexes of cyclobutadienes Pages 265-278 P. B. J. Driessen, H. Hogeveen

Issue 2, Pages 279-437 (22 August 1978)

Inorganic Syntheses : Volume XVII, A.G. MacDiarmid, editor-in-chief, McGraw-Hill, New York, 1977, xii + 223 pages, $23.95. Pages C51-C52 Dietmar Seyferth

Synthese des diphospha-1,1′-ferrocenes Pages C33-C36 Guillaume De Lauzon, François Mathey, Michel Simalty

Errata Page C53

Chemical and electrochemical oxidative cleavage reactions of compounds of the type η5-C5H5Fe(CO)2R Pages C37-C42 W. Rogers, J. A. Page, M. C. Baird

Phosphine induced reductive elimination reactions : Synthesis of ruthenium(O) fluorophosphine complexes Pages C43-C46 Abdul-Razzak Al-Ohaly, Robert A. Head, John F. Nixon

Sur la synthese de derives C-silicies d'aziridines Pages C25-C28 Françoise Duboudin, d'Odile Laporte

Derives heterodinucleaires pontes par le sulfure de carbone FeCS2Mn et FeCS2 Mo. Utilisation de complexes η2-CS2-Fer comme ligands Pages C29-C32 U. Oehmichen, T. G. Southern, H. Le Bozec, P. Dixneuf

Gmelin Handbook of Inorganic Chemistry : 8th Edition, New Supplement Series, Volume 49, “Organoiron Compounds. Part A, Ferrocene 2”, 1977, iv + 303 pages, DM 687, $ 316.10; Volume 0, “Organoiron Compounds, Part A, Ferrocene 3”, 1978, ii + 180 pages, DM 441, $202.90; J. Füssel, volume author, A. Slawisch, volume editor, Gmelin Institut für Anorganische Chemie der Max Planck Gesellschaft zur Förderung der Wissenschaften, Springer-Verlag, Berlin/Heidelberg/New York. Pages C49-C50 Dietmar Seyferth

Infrared and raman spectra of inorganic and coordination compounds : 3rd edition, K. Nakamoto, Wiley-Interscience, New York, 1978, xv + 448 pages, $24.50. Pages C47-C48 Dietmar Seyferth

gem-chloro(trimethylsilyl)allyllithium: A novel ambident nucleophile Pages 279-297 Dietmar Seyferth, Robert E. Mammarella

The reaction of 3,3-dichloroallyltrimethylsilane with n-butyllithium Pages 299-305 Dietmar Seyferth, Robert E. Mammarella

Ketones substituted with an alkali metal. Isolation and some properties Pages 307-316 L. Lochmann, Rajib L. De, J. Trekoval

Force constants of methylmercury(II) compounds Pages 317-321 J. Mink, P. L. Goggin

Gas phase nucleophilic substitution reactions; Transaminations of silanamines Pages 323-329 Kenneth J. Shea, Robert Gobeille, James F. Wolf

Heterogeneous reactions : VI. Reactions of trimethylchlorosilane, dimethyldichlorosilane and chloromethyldimethylchlorosilane with potassium t-butoxide and sodium methoxide Pages 331-340 Steven P. Hopper, Michael J. Tremelling, Emma W. Goldman

Spectres de vibration de composes organiques des elements de la colonne IVB : XI. Discussion de la structure des composes (CH3)3MN(CH3)2 (M = Si, Ge, Sn) a partir des spectres et du calcul des modes normaux de vibration Pages 341-358 Annette Marchand, Marie-Therese Forel, Monique Biviere-Baudet, Marie-Hélène Soulard

The preparation and tin-119m mössbauer spectra of tri-n-butylstannyl esters of heterocyclic and substituted aromatic carboxylic acids Pages 359-368 David W. Allen, John S. Brooks, Ralph Formstone, Alan J. Crowe and, Peter J. Smith

β-substituted alkyltin halides : I. Monoalkyltin trihalides: Synthetic, mechanistic and spectroscopic aspects Pages 369-382 Ronald E. Hutton, Joseph W. Burley, Vincent Oakes

Zur chemie des tris(cyclopentadienyl)uran(IV)-kations in wässriger lösung : II. Oligomere metallorganische tetracyanometallat-komplexe des uran(IV): Bis(tris(pentahapto-cyclopentadienyl)uran(IV))-tetracyanonickolat(II) bzw. -platinat(II) Pages 383-388 R. D. Fischer, G. R. Sienel

Komplexchemie polyfunktioneller liganden : XLIII. Schwingungsspektroskopische untersuchungen an metalltetracarbonyl-derivaten ditertiärer phosphine Pages 389-402 Helmut Gäbelein, Jochen Ellermann

Organomercury Compounds : XXIV Facile syntheses of polyfluoroarylmercurials by mercuration reactions Pages 403-426 G. B. Deacon, D. Tunaley

Anionic tricarbonyl derivatives of molybdenum and tungsten and their reactions with allyl halides Pages 427-437 Brian J. Brisdon, Dennis A. Edwards, James W. White